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期刊论文 19

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2023 4

2021 3

2020 1

2019 3

2017 1

2016 2

2015 1

2014 1

2009 1

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关键词

ITO 1

个旧锡矿 1

光纤激光器；被动锁模；可饱和吸收体；二硫化钛 1

回收 1

地球化学 1

废料 1

微波加热 1

微波装备 1

成矿作用演化 1

混酸溶浸—硫化沉锡工艺 1

熔炼 1

稳定同位素 1

铟 1

锡 1

锡粉 1

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Two-dimensional SnS2 nanosheets on Prussian blue template for high performance sodium ion batteries

Glenn J. Sim, Kakui Ma, Zhixiang Huang, Shaozhuan Huang, Ye Wang, Huiying Yang

《化学科学与工程前沿（英文）》 2019年第13卷第3期页码 493-500 doi: 10.1007/s11705-019-1826-z

摘要： Three-dimensional Prussian blue (PB) nanostructures was obtained via a one-step hydrothermal method. Subsequently, two-dimensional tin disulfide (SnS ) nanosheets were grown onto PB through a facile hydrothermal synthesis. The as prepared SnS /PB is further employed as the anode of sodium ion batteries (SIBs). SnS /PB nanoarchitecture delivers a specific capacity of 725.7 mAh∙g at 50 mA∙g . When put through more than 200 cycles, it achieved a stable cycling capacity of 400 mAh∙g at 200 mA∙g . The stable Na storage properties of SnS /PB was attributed to the synergistic effect among the conductive PB carbon, used as the template in this work. These results obtained potentially paves the way for the development of excellent electrochemical performance with stable performance of SIBs.

关键词： Prussian blue carbon nanocubes tin disulfide sodium ion batteries

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Molybdenum disulfide@nickel phyllosilicate hybrid for improving the flame retardancy and wear resistance

《化学科学与工程前沿（英文）》 2023年第17卷第12期页码 2114-2126 doi: 10.1007/s11705-023-2357-1

摘要： In this study, nickel phyllosilicate was synthesized based on molybdenum disulfide (MoS₂@NiPS) by the sol-gel method, and then MoS₂@NiPS was used to prepare epoxy composites. The thermal stability, flame retardancy, and frictional performances of epoxy composites were studied. With the addition of 3 wt% MoS₂@NiPS, the epoxy composite increased the limiting oxygen index from 23.8% to 26.1% and reduced the vertical burning time from 166 s for epoxy resin to 35 s. The residual char of the epoxy composite increased from 11.8 to 20.2 wt%. MoS₂@NiPS promoted the graphitization of the residual char, and facilitated the formation of a dense and continuous char layer, thereby improving the fire safety of epoxy resin. The epoxy composite with 3 wt% MoS₂@NiPS had excellent wear resistance property with a wear rate of 2.19 × 10⁻⁵ mm³·N^–1·m^–1, which was 68.8% lower than that of epoxy resin. This study presented a practical approach to improve the frictional and fire resistance of epoxy composites.

关键词： molybdenum disulfide nickel phyllosilicate epoxy resin flame retardancy

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Sub-nanometer finishing of polycrystalline tin by inductively coupled plasma-assisted cutting

《机械工程前沿（英文）》 2023年第18卷第3期 doi: 10.1007/s11465-023-0751-5

摘要： Polycrystalline tin is an ideal excitation material for extreme ultraviolet light sources. However, the existence of grain boundary (GB) limits the surface roughness of polycrystalline tin after single-point diamond turning (SPDT). In this work, a novel method termed inductively coupled plasma (ICP)-assisted cutting was developed for the sub-nanometer finishing of polycrystalline tin. The relationship between ICP power, processing time, and modification depth was established by thermodynamic simulation, and the fitted heat transfer coefficient of polycrystalline tin was 540 W/(m²·K). The effects of large-thermal-gradient ICP treatment on the microstructure of polycrystalline tin were studied. After 0.9 kW ICP processing for 3.0 s, corresponding to the temperature gradient of 0.30 K/µm, the grain size of polycrystalline tin was expanded from a size of approximately 20–80 μm to a millimeter scale. The Taguchi method was used to investigate the effects of rotational speed, depth of cut, and feed rate on SPDT. Experiments conducted based on the ICP system indicated that the plasma-assisted cutting method promoted the reduction of the influence of GB steps on the finishing of polycrystalline tin, thereby achieving a surface finish from 8.53 to 0.80 nm in Sa. The results of residual stress release demonstrated that the residual stress of plasma-assisted turning processing after 504 h stress release was 10.7 MPa, while that of the turning process without the ICP treatment was 41.6 MPa.

关键词： plasma-assisted cutting polycrystalline tin single-point diamond turning surface roughness

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Novel seed-assisted synthesis of indium tin oxide submicro-cubes and their resistivity

《化学科学与工程前沿（英文）》 2023年第17卷第5期页码 557-569 doi: 10.1007/s11705-022-2249-9

摘要： Indium tin oxide films, an important n-type semiconductor oxide, show great prospects in optoelectronic device applications. Consequently, as a key raw material of targets for sputtering films, it is important to prepare low-resistivity indium tin oxide powders. Herein, low-resistivity indium tin oxide submicro-cubes are synthesized by a seed-assisted coprecipitation method. The effects of seed content, In³⁺ concentration, aging time, reaction temperature and calcination temperature on resistivity were investigated by single factor and orthogonal experiments. To ensure reliability and reproducibility of data, each experiment was repeated three times and resistivity of each sample was measured three times to obtain average value. The results indicated that optimal sample was matched with cubic phase In₂O₃. The single-crystal indium tin oxide particles exhibited a regular cubic shape with a size of nearly 500 nm and low resistivity of 0.814 Ω·cm. Compared with particles prepared by the conventional coprecipitation method, indium tin oxide submicro-cubes showed good dispersion. The presence of seed particles provided nucleation sites with lower energy barriers and promoted formation of submicro-cubes. The face-to-face contact among particles and good dispersion contributed to electron transfer, resulting in lower resistivity. The seed-assisted synthesis provides a novel way to prepare low-resistivity indium tin oxide submicro-cubes.

关键词： indium tin oxide submicro-cubes resistivity seed-assisted coprecipitation method orthogonal experiment

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Uncovering the evolution of tin use in the United States and its implications

《环境科学与工程前沿（英文）》 2021年第15卷第6期 doi: 10.1007/s11783-021-1406-6

摘要：

• US tin use decreases as the GDP value added by manufacturing sector increases.

关键词： Tin use GDP Curve fitting Logistic model Gompertz model

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grown TiN/N-TiO composite for enhanced photocatalytic H evolution activity

《能源前沿（英文）》 2021年第15卷第3期页码 721-731 doi: 10.1007/s11708-021-0766-8

摘要： Titanium nitride (TiN) decorated N-doped titania (N-TiO₂) composite (TiN/N-TiO₂) is fabricated via an in situ nitridation using a hydrothermally synthesized TiO₂ and melamine (MA) as raw materials. After the optimization of the reaction condition, the resultant TiN/N-TiO₂ composite delivers a hydrogen evolution activity of up to 703 μmol/h under the full spectrum irradiation of Xe-lamp, which is approximately 2.6 and 32.0 times more than that of TiO₂ and TiN alone, respectively. To explore the underlying photocatalytic mechanism, the crystal phase, morphology, light absorption, energy band structure, element composition, and electrochemical behavior of the composite material are characterized and analyzed. The results indicate that the superior activity is mainly caused by the in situ formation of plasmonic TiN and N-TiO₂ with intimate interface contact, which not only extends the spectral response range, but also accelerates the transfer and separation of the photoexcited hot charge carrier of TiN. The present study provides a fascinating approach to in situ forming nonmetallic plasmonic material/N-doped TiO₂ composite photocatalysts for high-efficiency water splitting.

关键词： photocatalytic H₂ evolution TiN/N-TiO₂ composite plasmonic effect in-situ nitridation

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Electrochemical oxidation of humic acid at the antimony- and nickel-doped tin oxide electrode

TANG Chengli,YAN Wei,ZHENG Chunli

《环境科学与工程前沿（英文）》 2014年第8卷第3期页码 337-344 doi: 10.1007/s11783-013-0545-9

摘要： This work investigated the degradation of humic acid (HA) in aqueous solution by electrochemical oxidation with Antimony- and Nickel-doped Tin oxide electrode (Ni-Sb-SnO /Ti electrode) as the anode. Initial concentrations of HA ranged from 3 to 9 mg·L . Under such a concentration scope, the degradation of HA was a mass transfer controlled process. Degradation rate increased with the increase of HA initial concentration. Test on the effect of tert-butanol revealed that ·OH played an important role in the oxidation of HA. The absence of cation Ca was beneficial to HA degradation, which suggested that both indirect and direct electrolyze happened during the whole electrochemical oxidation process. Alkaly (pH= 12) and neutral (pH= 7) conditions were benefical to HA degradation.

关键词： electrochemical oxidation humic acid (HA) natural water Ni-Sb-SnO₂/Ti electrode

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混酸溶浸—硫化沉锡工艺处理ITO废料回收铟锡

王树楷

《中国工程科学》 2009年第11卷第9期页码 34-37

摘要：

采用混酸溶浸—硫化沉锡工艺处理ITO废料，解决了料液难滤和有效回收铟和锡的问题。

关键词： ITO 废料铟锡混酸溶浸—硫化沉锡工艺

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云锡公司的锡冶金技术跃居世界先进水平

《中国工程科学》 2004年第6卷第7期页码 94-94

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微波熔炼在锡粉回收中的工业应用 Article

许磊, 彭金辉, 白海龙, Srinivasakannan C., 张利波, 吴庆田, 韩朝晖, 郭胜惠, 巨少华, 杨黎

《工程（英文）》 2017年第3卷第3期页码 423-427 doi: 10.1016/J.ENG.2017.03.006

摘要：

本文探讨了微波加热在工业锡粉熔化中的应用。对离心雾化法制备的金属锡粉的形貌和粒径进行了表征锡粉颗粒均且呈球形，90% 的颗粒粒径为38~75 μm。过介电性能测试，研究了锡粉的微波吸收特性微波的穿作用对锡粉具有良好的整体加热能。温度高于150℃时，微波加热锡粉的主要机制是电导损耗设计开发了20 kW 微波熔炼锡合金装备，并将其应用于产业化该装备的加热率与常规方法相比能提高10 倍以上，缩短了熔炼工艺研究结果表明，微波加热加快了升温率，缩短了熔炼时间，锡回收率为97.79%，渣量仅为1.65%，其他损失低于0.56%；单位能耗仅为0.17 kW·h·kg⁻¹远低于传统方法所要的能量。因此微波冶炼提高了加热效率，降低了能耗。

关键词：微波加热熔炼锡粉微波装备回收

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TIN2012-34003 and TIN2013-47074-C2-1-R) and FPU Scholarship (FPU13/03141) from the Spanish Government

Miguel OLIVER,Francisco MONTERO,José Pascual MOLINA,Pascual GONZÁLEZ,Antonio FERNÁNDEZ-CABALLERO

《信息与电子工程前沿（英文）》 2016年第17卷第4期页码 348-364 doi: 10.1631/FITEE.1500347

摘要： This paper seeks to determine how the overlap of several infrared beams affects the tracked position of the user, depending on the angle of incidence of light, distance to the target, distance between sensors, and the number of capture devices used. We also try to show that under ideal conditions using several Kinect sensors increases the precision of the data collected. The results obtained can be used in the design of telerehabilitation environments in which several RGB-D cameras are needed to improve precision or increase the tracking range. A numerical analysis of the results is included and comparisons are made with the results of other studies. Finally, we describe a system that implements intelligent methods for the rehabilitation of patients based on the results of the tests carried out.

关键词： Kinect sensor Rehabilitation system Capture precision Multi-camera system

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Recent progress in MoS

Soheil RASHIDI, Akshay CARINGULA, Andy NGUYEN, Ijeoma OBI, Chioma OBI, Wei WEI

《能源前沿（英文）》 2019年第13卷第2期页码 251-268 doi: 10.1007/s11708-019-0625-z

摘要： In an era of graphene-based nanomaterials as the most widely studied two-dimensional (2D) materials for enhanced performance of devices and systems in solar energy conversion applications, molybdenum disulfide (MoS ) stands out as a promising alternative 2D material with excellent properties. This review first examined various methods for MoS synthesis. It, then, summarized the unique structure and properties of MoS nanosheets. Finally, it presented the latest advances in the use of MoS nanosheets for important solar energy applications, including solar thermal water purification, photocatalytic process, and photoelectrocatalytic process.

关键词： 2D nanomaterial molybdenum disulfide solar energy conversion solar thermal conversion photocatalytst photoelectrocatalyst

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个旧锡矿地球化学及成矿作用演化

秦德先,黎应书,范柱国,陈爱兵,谈树成,洪托,李连举,林小平

《中国工程科学》 2006年第8卷第1期页码 30-39

摘要：

关于个旧锡矿床的成因，过去多数人持“花岗岩岩浆期后热液成矿”观点。笔者的研究成果表明，个旧锡矿具有多期、多源成矿，可划分为3个成矿系列，即印支期海底基性火山成矿系列、海底喷流成矿系列和燕山晚期花岗岩改造（叠加）成矿系列，成矿模式可归结为“裂谷环境—火山沉积—喷流热水沉积—花岗岩叠加改造”；在划分成矿系列的基础上，重点从矿床的微量及稀土元素、稳定同位素及流体包裹方面来论证新的成矿观点。

关键词：个旧锡矿地球化学稳定同位素成矿作用演化

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Utilizing transparent and conductive SnO

Jing Gu, Hongtao Yu, Xie Quan, Shuo Chen, Junfeng Niu

《环境科学与工程前沿（英文）》 2020年第14卷第4期 doi: 10.1007/s11783-020-1251-z

摘要： Abstract • A novel Z-scheme Si-SnO2-TiOx with SnO2 as electron mediator is first constructed. • Transparent and conductive SnO2 can pass light through and promote charge transport. • VO from SnO2 and TiOx improve photoelectrochemical performances. • Efficient photocatalytic degradations originate from the Z scheme construction. Z-scheme photocatalysts, with strong redox ability, have a great potential for pollutants degradation. However, it is challenging to construct efficient Z-scheme photocatalysts because of their poor interfacial charge separation. Herein, by employing transparent and conductive SnO2 as electron mediator to pass light through and promote interfacial charge transportation, a novel Z-scheme photocatalyst Si-SnO2-TiOx (1

关键词： Z-scheme photocatalyst Tin oxide Electron mediator Organic pollutant

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Wheat gluten protein and its impacts on wheat processing quality

Wujun MA, Zitong YU, Maoyun SHE, Yun ZHAO, Shahidul ISLAM

《农业科学与工程前沿（英文）》 2019年第6卷第3期页码 279-287 doi: 10.15302/J-FASE-2019267

摘要：

Before the advent of the wheat genomic era, a wide range of studies were conducted to understand the chemistry and functions of the wheat storage proteins, which are the major determinants of wheat flour the suitability of wheat flour for various end products, such as bread, noodles and cakes. Wheat grain protein is divided into gluten and non-gluten fractions and the wheat processing quality mainly depends on the gluten fractions. Gluten provides the unique extensibility and elasticity of dough that are essential for various wheat end products. Disulfide bonds are formed between cysteine residues, which is the chemical bases for the physical properties of dough. Based on the SDS-extractability, grain protein is divided into SDS-unextractable polymeric protein (UPP) and SDS-extractable polymeric protein. The percentage of UPP is positively related to the formation of disulfide bonds in the dough matrix. In the wheat genomic era, new glutenins with long repetitive central domains that contain a high number of consensus hexapeptide and nonapeptide motifs as well as high content of cysteine and glutamine residues should be targeted.

关键词： wheat gluten consensus motifs disulfide bonds SDS-unextractable polymeric protein glutenins gliadins processing quality storage protein